IBS-Catalyzed Regioselective Oxidation of Phenols to 1,2-Quinones with Oxone®
نویسندگان
چکیده
منابع مشابه
IBS-catalyzed regioselective oxidation of phenols to 1,2-quinones with Oxone®.
We have developed the first example of hypervalent iodine(V)-catalyzed regioselective oxidation of phenols to o-quinones. Various phenols could be oxidized to the corresponding o-quinones in good to excellent yields using catalytic amounts of sodium salts of 2-iodobenzenesulfonic acids (pre-IBSes) and stoichiometric amounts of Oxone® as a co-oxidant under mild conditions. The reaction rate of I...
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ژورنال
عنوان ژورنال: Molecules
سال: 2012
ISSN: 1420-3049
DOI: 10.3390/molecules17078604